دانلود Polyurethane microcapsules for self-healing paint coatings

ترجمه فارسی Polyurethane microcapsules for self-healing paint coatings
قیمت : 285,000 ریال
شناسه محصول : 2009439
نویسنده/ناشر/نام مجله : Rsc Advances
سال انتشار: 2014
تعداد صفحات انگليسي : 10
نوع فایل های ضمیمه : pdf+word
حجم فایل : 1 Mb
کلمه عبور همه فایلها : www.daneshgahi.com
عنوان انگليسي : Polyurethane microcapsules for self-healing paint coatings

چکیده

Abstract

Polyurethane microcapsules containing water-borne polyurethane (PU) paint as a core material for selfrepairing protection coatings were successfully manufactured via interfacial polymerization of dioldiisocyanate prepolymer and 1,4-butanediol as a chain extender in an emulsion solution. The chemical structure of the resultant microcapsules was characterized by Fourier Transform Infrared Spectroscopy. Spherical capsules were observed with an average diameter of 39–72 mm and average shell thickness of 3.8-5.5 mm, while controlling agitation rates (2000–8000 rpm). The PU shell wall thickness was linearly proportional to the measured capsule diameter, thus, showing that the ratio of capsule wall thickness to diameter was constant (0.08). The typical core content and synthetic yield of the filled capsules were approximately 44–59 wt% and 31–67%, respectively. Thermal gravimetric analysis and scanning electron microscopy results support the determined thermal stability and morphology of the samples. Scratch tests, used to evaluate self-healing protection coating systems, showed that these materials had significant ability to recover from damage on the substrate, depending on the diameter and theconcentration of the PU capsules in the paint layer, which could control the efficiency.

Keywords: self-healing paint

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